Originally Posted by
a-b-c-d-9-8-7
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Well, the deluxe edition content (the gameplay one, at least) should already be a part of the game you download without having to download anything extra. The big download button you see next to the Deluxe edition extra content SHOULD download stuff like the soundtrack, Lineage movie and a couple of other extras. I tried doing it myself and as you said, it doesn't start downloading anything, so there are clearly some issues with this extra content and Ubi should look into what's wrong (thanks in advance if you look into it, guys).
Then again, you are not the first person to have issues with Deluxe editions of some older Ubi games. I had some issues with Far Cry 3 Deluxe edition not connecting to Uplay servers (I can't remember how I fixed that) and I had a long-term issue of connecting to AC Brotherhood servers with my Deluxe edition (I texted the support many times and I even told them that the solution that fixed it for me was getting Uplay+ and activating the AC Brotherhood Deluxe edition from there, which means that there definitely was something wrong with the way Deluxe editions connected to Uplay servers - it's almost like they weren't activated at all). I told Ubi support on Twitter anything they could have needed for this issue, but I'm not sure it ever got resolved (or even if anyone in the technical support heard about this). If it's still an issue, then it would be great if someone at Ubi looked into what's wrong.
Anyway, does your multiplayer work at all? Are the 2 characters simply missing there?