Where you go depends on what you want to do....especially with 1.81 giving tonnes of DTech fairly easily now. Your first focus would probably be to either get, or to optimize, your gear sets. You should probably run over-world bosses, this takes a little under 1 hour per run, and can be completed once every four hours. the first run i did with the drop rate increases gave me 4 exotics, the second run gave me 2, and subsequent runs gave me on average 1 exotic OR 1 classified (not sure why my first run was so successful but it was probably to whet my appetite for the new patch) you can find the route/guides on youtube
If you want to run missions, I would go to matchmaking and run challenging Lexington, as its not too difficult to find 3 other agents just looking to grind it out, completing the weekly missions is a good way to get exotics and DTech and you can complete 2 per character per week
I would avoid Underground unless you are specifically targeting commendations, or the second weekly cache from it
Darkzone runs can be mixed bag, as there are a lot of less than friendly people that like to go there and literally ruin people's day, but are required to get both the weekly and 1 of the daily caches (you can easily get 3/4 daily caches just from spending 30 minutes or less in the DZ so why not right?)
Resistance farming is not as good in my opinion as a lot of people say it is....especially if you don't have a full group already set up to run it with you, but if you want to try it out dont let me stop you...as long as you have a group with a full reclaimer all ready to go
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